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CLASS 12 • CHEMISTRY • CHAPTER 2

Electrochemistry

High-yield revision notes, key concepts, formulas, and CBSE board examination questions for Class 12 Chemistry.

Nernst Equation

For electrochemical cell reaction $aA + bB \rightarrow cC + dD$ at $298\text{ K}$:

$$E_{\text{cell}} = E^\circ_{\text{cell}} - \frac{0.0591}{n}\log_{10} \frac{[C]^c [D]^d}{[A]^a [B]^b}$$

$$\Delta G^\circ = -n F E^\circ_{\text{cell}} = -2.303 RT \log K_c$$


Kohlrausch's Law of Independent Migration

Limiting molar conductivity ($\Lambda_m^\circ$) of an electrolyte is the sum of individual ionic conductivities of its cations and anions:

$$\Lambda_m^\circ (\text{NaCl}) = \lambda^\circ(\text{Na}^+) + \lambda^\circ(\text{Cl}^-)$$

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